POLYMER BLENDS AND ALLOYS
Ouvrage 0-7514-0081-5 : POLYMER BLENDS AND ALLOYS
Mixing two or more polymers together to produce a
blend (or 'alloy') is one
well-established strategy for achieving a specified
portfolio of physical
properties, without the need to synthesize
specialized polymer systems. The
subject is vast and has been the focus of much
work, both theoretical and
experimental. Much of the earlier work in this
field was necessarily empircal and
many of the blends produced were of academic rather
than commercial interest.
The manner in which the two (or more) polymers are
compounded together is of
vital importance in controlling the properties of
the blend. Moreover, particularly
through detailed rheological studies, it is
becoming apparent that processing can
provide a wide range of blend microstructures. This
is exemplified by the 'in situ'
formation of fibres resulting from the imposition
of predetermined flow fields on
blends, when in the solution or melt state. The
microstructures produced in this
case transform the blend into a true fibre
composite; this parallels earlier work
on the deformation of metal alloys. This type of
processing-structure-property
correlation opens up many new possibilities for
innovative applications; for
example, the production of stiff fibre composites
and blends having anisotropic
transport properties, e.g. novel membranes. This is
an authorititive and
up-to-date survey of the technology available to
synthesize and test polymer
blends and alloys, and of the future applications
which developments in
processing are offering. Emphasis is on the
properties required by industry and
how these properties can be achieved and tested.
The book is intended for
polymer chemists, engineers and materials
technologists in the chemical, process
and allied industries, and in academic and research
institutions.
Table of Contents
1
Introduction
1
2
Practical aspects of processing blends
7
3
Compatibilisation and reactive blending
46
4
Rheology of polymer blends
75
5
Practical techniques for studying blend
microstructure
103
6
Theoretical aspects of polymer blends
and alloys
126
7
Toughened polymers
163
8
Blends containing liquid crystal
polymers
195
9
Fibre forming and in situ fibre
composites
228
Index
257
Auteur : FOLKES
Editeur : BLACKIE
Nombre de pages : 272
Date de publication : 10 1993
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